抄録
The synthesis of a novel hydrocarbon, dibarrelane, has been accomplished in 11 steps via an intramolecular REDDA reaction of a masked o-benzoquinone, followed by Clemmensen reduction and Barton decarboxylation. The twisted structure of the tetracyclic dibarrelane skeleton was also clarified via X-ray crystallography. Finally, it was proposed that dibarrelane has C2 symmetry rather than C2v symmetry.
本文言語 | English |
---|---|
ページ(範囲) | 2803-2808 |
ページ数 | 6 |
ジャーナル | Journal of Organic Chemistry |
巻 | 79 |
号 | 6 |
DOI | |
出版ステータス | Published - 2014 3月 21 |
ASJC Scopus subject areas
- 有機化学