Synthesis of diphenylnitroxide-substituted polystyrenes and their p- and n-type redox property

Masashi Fujinaga, Takeo Suga, Hiroyuki Nishide

研究成果: Paper査読

抄録

Diphenylnitroxide derivatives are known to their high radical stability and stable redox properties suitable as an electrode-active material of the next generation secondary battery. A series of p, p'-disubstituted diphenylnitroxide derivatives were synthesized, and p-substituent effect on their redox properties were investigated by electrochemical measurements. Styrene derivative bearing the diphenylnitroxide radical was synthesized via 4 steps, and polymerized to give the precursor polymer (Mn =3.2 × 103). Chemical oxidation of this polymer yielded the corresponding radical polymer. Its redox behavior will be also reported.

本文言語English
ページ数1
出版ステータスPublished - 2006 12 1
イベント55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
継続期間: 2006 9 202006 9 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

ASJC Scopus subject areas

  • Engineering(all)

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