Diphenylnitroxide derivatives are known to their high radical stability and stable redox properties suitable as an electrode-active material of the next generation secondary battery. A series of p, p'-disubstituted diphenylnitroxide derivatives were synthesized, and p-substituent effect on their redox properties were investigated by electrochemical measurements. Styrene derivative bearing the diphenylnitroxide radical was synthesized via 4 steps, and polymerized to give the precursor polymer (Mn =3.2 × 103). Chemical oxidation of this polymer yielded the corresponding radical polymer. Its redox behavior will be also reported.
|出版ステータス||Published - 2006 12 1|
|イベント||55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan|
継続期間: 2006 9 20 → 2006 9 22
|Other||55th Society of Polymer Science Japan Symposium on Macromolecules|
|Period||06/9/20 → 06/9/22|
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