A hydrogenated TiO2-reduced-graphene oxide (H-TiO 2-RGO) nanocomposite is synthesised via a facile one-pot hydrogenation treatment process. The morphologies and structures are characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The nitrogen adsorption-desorption isotherms revealed that the H-TiO 2-RGO exhibited large specific surface area of 114.4 m2 g-1. Compared with the TiO2-RGO nanocomposite, the H-TiO2-RGO nanocomposite exhibits a much higher rate capability and better capacity retention. At a current rate of 5 C, the reversible capacity of the H-TiO2-RGO electrode is up to 166.3 mA h g-1 and with only 2.4% capacity loss after 100 cycles. The excellent electrochemical performance is strongly related to the high electronic conductivity derived from hydrogenated TiO2 frameworks and the good contact between the zero-dimensional (0D) H-TiO2 nanoparticles with two-dimensional (2D) reduced-graphene oxide nanosheets, which efficiently shortened the Li + diffusion path lengths, enhanced the electrolyte-active material contact area and facilitated rapid e- transfer.
ASJC Scopus subject areas
- 化学 (全般)