Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces

T. Yanagisawa, C. Yokoyama, K. Kuroda, C. Kato

研究成果: Article査読

21 被引用数 (Scopus)

抄録

Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.

本文言語English
ページ(範囲)47-50
ページ数4
ジャーナルBulletin of the Chemical Society of Japan
63
1
DOI
出版ステータスPublished - 1990

ASJC Scopus subject areas

  • 化学 (全般)

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