Synthesis of multicyclic heterocycles initiated by c-h bond activation along with "rollover" using a Rh(III) catalyst

Takanori Shibata*, Satoshi Takayasu

*この研究の対応する著者

研究成果: Article査読

14 被引用数 (Scopus)

抄録

Various multicyclic heterocycles were synthesized via "rollover" as the key pathway using a Rh(III) catalyst with a catalytic amount of sodium pivalate or copper(II) acetate. 3-Alkynyl-2-heteroarylpyridines were transformed into tri- or tetracyclic heterocycles containing two heteroatoms via an intramolecular alkyne insertion. 3-Aryloyl-2-arylpyridines were derived into 4-azafluoren-9-ols via the intramolecular carbonyl insertion.

本文言語English
ページ(範囲)379-388
ページ数10
ジャーナルHeteroatom Chemistry
25
5
DOI
出版ステータスPublished - 2014 11月 1

ASJC Scopus subject areas

  • 化学 (全般)

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