Synthesis of nitroxide-substituted polystyrene and its n-type redox property

Shinji Kasatori; Takeo Suga; Hiroyuki Nishide

Synthesis of nitroxide-substituted polystyrene and its n-type redox property

Shinji Kasatori^*, Takeo Suga, Hiroyuki Nishide

^*この研究の対応する著者

先進理工学部

研究成果: Paper › 査読

抄録

The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

本文言語	English
ページ数	1
出版ステータス	Published - 2005 12月 1
イベント	54th SPSJ Symposium on Macromolecules - Yamagata, Japan 継続期間: 2005 9月 20 → 2005 9月 22

Other

Other	54th SPSJ Symposium on Macromolecules
国/地域	Japan
City	Yamagata
Period	05/9/20 → 05/9/22

ASJC Scopus subject areas

工学（全般）

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引用スタイル

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abstract = "The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.",

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author = "Shinji Kasatori and Takeo Suga and Hiroyuki Nishide",

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AU - Kasatori, Shinji

AU - Suga, Takeo

AU - Nishide, Hiroyuki

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Y1 - 2005/12/1

N2 - The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

AB - The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

KW - Electrode-active material

KW - Nitroxide radical

KW - Radical Polymer

KW - Redox property

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M3 - Paper

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T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Synthesis of nitroxide-substituted polystyrene and its n-type redox property

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