Synthesis of nitroxide-substituted polystyrene and its n-type redox property

Shinji Kasatori; Takeo Suga; Hiroyuki Nishide

Synthesis of nitroxide-substituted polystyrene and its n-type redox property

Shinji Kasatori, Takeo Suga, Hiroyuki Nishide

先進理工学部

研究成果: Paper › 査読

抄録

The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

本文言語	English
ページ数	1
出版ステータス	Published - 2005 12 1
イベント	54th SPSJ Symposium on Macromolecules - Yamagata, Japan 継続期間: 2005 9 20 → 2005 9 22

Other

Other	54th SPSJ Symposium on Macromolecules
Country	Japan
City	Yamagata
Period	05/9/20 → 05/9/22

ASJC Scopus subject areas

Engineering(all)

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引用スタイル

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abstract = "The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.",

keywords = "Electrode-active material, Nitroxide radical, Radical Polymer, Redox property",

author = "Shinji Kasatori and Takeo Suga and Hiroyuki Nishide",

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AU - Kasatori, Shinji

AU - Suga, Takeo

AU - Nishide, Hiroyuki

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

AB - The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

KW - Electrode-active material

KW - Nitroxide radical

KW - Radical Polymer

KW - Redox property

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Y2 - 20 September 2005 through 22 September 2005

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