Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization

Kimihisa Yamamoto, Kenichi Oyaizu, Eishun Tsuchida

    研究成果: Article

    10 引用 (Scopus)

    抄録

    Photo‐oxidation of bis(3,5‐dimethylphenyl) disulfide proceeds in the presence of aromatic nitriles as sensitizers. Catalytic amounts of 9,10‐dicyanoanthracene act as an electron mediator of the transfer from the disulfide to oxygen in the presence of biphenyl as a co‐sensitizer. The photo‐redox system enabled an efficient formation of poly(thio‐2,6‐dimethyl‐1,4‐phenylene) through electrophilic reaction of the sulfonium cation produced in the photo‐oxidation.

    元の言語English
    ページ(範囲)3087-3094
    ページ数8
    ジャーナルMacromolecular Chemistry and Physics
    195
    発行部数9
    DOI
    出版物ステータスPublished - 1994

    Fingerprint

    Photooxidation
    photooxidation
    disulfides
    Sulfides
    Disulfides
    sulfides
    polymerization
    Polymerization
    Nitriles
    nitriles
    synthesis
    Cations
    Positive ions
    Oxygen
    cations
    Electrons
    oxygen
    electrons
    diphenyl

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Physical and Theoretical Chemistry
    • Organic Chemistry
    • Polymers and Plastics
    • Materials Chemistry

    これを引用

    Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization. / Yamamoto, Kimihisa; Oyaizu, Kenichi; Tsuchida, Eishun.

    :: Macromolecular Chemistry and Physics, 巻 195, 番号 9, 1994, p. 3087-3094.

    研究成果: Article

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