Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization

Kimihisa Yamamoto; Kenichi Oyaizu; Eishun Tsuchida

doi:10.1002/macp.1994.021950907

Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization

Kimihisa Yamamoto, Kenichi Oyaizu, Eishun Tsuchida

先進理工学部

研究成果: Article

10 引用（Scopus）

抜粋

Photo‐oxidation of bis(3,5‐dimethylphenyl) disulfide proceeds in the presence of aromatic nitriles as sensitizers. Catalytic amounts of 9,10‐dicyanoanthracene act as an electron mediator of the transfer from the disulfide to oxygen in the presence of biphenyl as a co‐sensitizer. The photo‐redox system enabled an efficient formation of poly(thio‐2,6‐dimethyl‐1,4‐phenylene) through electrophilic reaction of the sulfonium cation produced in the photo‐oxidation.

元の言語	English
ページ（範囲）	3087-3094
ページ数	8
ジャーナル	Macromolecular Chemistry and Physics
巻	195
発行部数	9
DOI	https://doi.org/10.1002/macp.1994.021950907
出版物ステータス	Published - 1994 9

フィンガープリント

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Organic Chemistry
Polymers and Plastics
Materials Chemistry

これを引用

Yamamoto, K., Oyaizu, K., & Tsuchida, E. (1994). Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization. Macromolecular Chemistry and Physics, 195(9), 3087-3094. https://doi.org/10.1002/macp.1994.021950907

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文献にアクセス

10.1002/macp.1994.021950907