Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization

Kimihisa Yamamoto, Kenichi Oyaizu, Eishun Tsuchida

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Photo‐oxidation of bis(3,5‐dimethylphenyl) disulfide proceeds in the presence of aromatic nitriles as sensitizers. Catalytic amounts of 9,10‐dicyanoanthracene act as an electron mediator of the transfer from the disulfide to oxygen in the presence of biphenyl as a co‐sensitizer. The photo‐redox system enabled an efficient formation of poly(thio‐2,6‐dimethyl‐1,4‐phenylene) through electrophilic reaction of the sulfonium cation produced in the photo‐oxidation.

本文言語English
ページ(範囲)3087-3094
ページ数8
ジャーナルMacromolecular Chemistry and Physics
195
9
DOI
出版ステータスPublished - 1994 9

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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