抄録
Photo‐oxidation of bis(3,5‐dimethylphenyl) disulfide proceeds in the presence of aromatic nitriles as sensitizers. Catalytic amounts of 9,10‐dicyanoanthracene act as an electron mediator of the transfer from the disulfide to oxygen in the presence of biphenyl as a co‐sensitizer. The photo‐redox system enabled an efficient formation of poly(thio‐2,6‐dimethyl‐1,4‐phenylene) through electrophilic reaction of the sulfonium cation produced in the photo‐oxidation.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 3087-3094 |
| ページ数 | 8 |
| ジャーナル | Macromolecular Chemistry and Physics |
| 巻 | 195 |
| 発行部数 | 9 |
| DOI | |
| 出版物ステータス | Published - 1994 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Organic Chemistry
- Polymers and Plastics
- Materials Chemistry
これを引用
Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization. / Yamamoto, Kimihisa; Oyaizu, Kenichi; Tsuchida, Eishun.
：: Macromolecular Chemistry and Physics, 巻 195, 番号 9, 1994, p. 3087-3094.研究成果: Article
}
TY - JOUR
T1 - Synthesis of poly(2,6‐dimethylphenylene sulfide) by photooxidative polymerization
AU - Yamamoto, Kimihisa
AU - Oyaizu, Kenichi
AU - Tsuchida, Eishun
PY - 1994
Y1 - 1994
N2 - Photo‐oxidation of bis(3,5‐dimethylphenyl) disulfide proceeds in the presence of aromatic nitriles as sensitizers. Catalytic amounts of 9,10‐dicyanoanthracene act as an electron mediator of the transfer from the disulfide to oxygen in the presence of biphenyl as a co‐sensitizer. The photo‐redox system enabled an efficient formation of poly(thio‐2,6‐dimethyl‐1,4‐phenylene) through electrophilic reaction of the sulfonium cation produced in the photo‐oxidation.
AB - Photo‐oxidation of bis(3,5‐dimethylphenyl) disulfide proceeds in the presence of aromatic nitriles as sensitizers. Catalytic amounts of 9,10‐dicyanoanthracene act as an electron mediator of the transfer from the disulfide to oxygen in the presence of biphenyl as a co‐sensitizer. The photo‐redox system enabled an efficient formation of poly(thio‐2,6‐dimethyl‐1,4‐phenylene) through electrophilic reaction of the sulfonium cation produced in the photo‐oxidation.
UR - http://www.scopus.com/inward/record.url?scp=0000523443&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000523443&partnerID=8YFLogxK
U2 - 10.1002/macp.1994.021950907
DO - 10.1002/macp.1994.021950907
M3 - Article
AN - SCOPUS:0000523443
VL - 195
SP - 3087
EP - 3094
JO - Macromolecular Chemistry and Physics
JF - Macromolecular Chemistry and Physics
SN - 1022-1352
IS - 9
ER -