Synthesis of Polycyclic and Cage Siloxanes by Hydrolysis and Intramolecular Condensation of Alkoxysilylated Cyclosiloxanes

Tomoaki Sugiyama, Hiroya Shiba, Masashi Yoshikawa, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda

研究成果: Article

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The controlled synthesis of oligosiloxanes with well-defined structures is important for the bottom-up design of siloxane-based nanomaterials. This work reports the synthesis of various polycyclic and cage siloxanes by the hydrolysis and intramolecular condensation of monocyclic tetra- and hexasiloxanes functionalized with various alkoxysilyl groups. An investigation of monoalkoxysilylated cyclosiloxanes revealed that intramolecular condensation occurred preferentially between adjacent alkoxysilyl groups to form new tetrasiloxane rings. The study of dialkoxy- and trialkoxysilylated cyclotetrasiloxanes revealed multistep intramolecular condensation reactions to form cubic octasiloxanes in relatively high yields. Unlike conventional methods starting from organosilane monomers, intramolecular condensation enables the introduction of different organic substituents in controlled arrangements. So-called Janus cubes have been successfully obtained, that is, Ph 4 R 4 Si 8 O 12 , in which R=Me, OSiMe 3 , and OSiMe 2 Vi (Vi=vinyl). These findings will enable the creation of siloxane-based materials with diverse functions.

元の言語English
ページ(範囲)2764-2772
ページ数9
ジャーナルChemistry - A European Journal
25
発行部数11
DOI
出版物ステータスPublished - 2019 2 21

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ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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