Synthesis of polyphenylene thioethers through cationic oxidative polymerization

Eishun Tsuchida; Kimihisa Yamamoto; Mitsutoshi Jikei; Eiichi Shouji; Hiroyuki Nishide

Synthesis of polyphenylene thioethers through cationic oxidative polymerization

Eishun Tsuchida, Kimihisa Yamamoto, Mitsutoshi Jikei, Eiichi Shouji, Hiroyuki Nishide

理工学術院総合研究所

研究成果: Article › 査読

9 被引用数 (Scopus)

抄録

Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.

本文言語	English
ページ（範囲）	1285-1298
ページ数	14
ジャーナル	Journal of macromolecular science. Chemistry
巻	A28
号	11-12
出版ステータス	Published - 1991 11

ASJC Scopus subject areas

Engineering(all)

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引用スタイル

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abstract = "Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.",

author = "Eishun Tsuchida and Kimihisa Yamamoto and Mitsutoshi Jikei and Eiichi Shouji and Hiroyuki Nishide",

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T1 - Synthesis of polyphenylene thioethers through cationic oxidative polymerization

AU - Tsuchida, Eishun

AU - Yamamoto, Kimihisa

AU - Jikei, Mitsutoshi

AU - Shouji, Eiichi

AU - Nishide, Hiroyuki

PY - 1991/11

Y1 - 1991/11

N2 - Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.

AB - Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.

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