Synthesis of polyphenylene thioethers through cationic oxidative polymerization

Eishun Tsuchida; Kimihisa Yamamoto; Mitsutoshi Jikei; Eiichi Shouji; Hiroyuki Nishide

Synthesis of polyphenylene thioethers through cationic oxidative polymerization

Eishun Tsuchida^*, Kimihisa Yamamoto, Mitsutoshi Jikei, Eiichi Shouji, Hiroyuki Nishide

^*この研究の対応する著者

理工学術院総合研究所

研究成果: Article › 査読

9 被引用数 (Scopus)

抄録

Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.

本文言語	English
ページ（範囲）	1285-1298
ページ数	14
ジャーナル	Journal of macromolecular science. Chemistry
巻	A28
号	11-12
出版ステータス	Published - 1991 11月

ASJC Scopus subject areas

工学（全般）

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引用スタイル

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title = "Synthesis of polyphenylene thioethers through cationic oxidative polymerization",

abstract = "Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.",

author = "Eishun Tsuchida and Kimihisa Yamamoto and Mitsutoshi Jikei and Eiichi Shouji and Hiroyuki Nishide",

year = "1991",

month = nov,

language = "English",

volume = "A28",

pages = "1285--1298",

journal = "Journal of Macromolecular Science - Pure and Applied Chemistry",

issn = "1060-1325",

publisher = "Taylor and Francis Ltd.",

number = "11-12",

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TY - JOUR

T1 - Synthesis of polyphenylene thioethers through cationic oxidative polymerization

AU - Tsuchida, Eishun

AU - Yamamoto, Kimihisa

AU - Jikei, Mitsutoshi

AU - Shouji, Eiichi

AU - Nishide, Hiroyuki

PY - 1991/11

Y1 - 1991/11

N2 - Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.

AB - Polyaromatic sulfides are efficiently and conveniently prepared by cationic oxidative polymerization. Diphenyl disulfides are quantitatively polymerized to yield poly(p-phenylene sulfide)s as white powders whose structure predominantely contains 1,4-phenylene sulfide bonds. The disulfides are oxidized to phenylbis(phenylthio)- sulfonium cations as active species of the polymerization. Repeating the oxidation and electrophilic reaction of the cation to the p-position of disulfides yields the polymer.

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M3 - Article

AN - SCOPUS:0026258295

VL - A28

SP - 1285

EP - 1298

JO - Journal of Macromolecular Science - Pure and Applied Chemistry

JF - Journal of Macromolecular Science - Pure and Applied Chemistry

SN - 1060-1325

IS - 11-12

ER -

Synthesis of polyphenylene thioethers through cationic oxidative polymerization

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