Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

Hiroki Ohshiro; Takeo Suga; Hiroyuki Nishide

Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

Hiroki Ohshiro, Takeo Suga, Hiroyuki Nishide

先進理工学部

研究成果: Paper › 査読

抄録

Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (M_n=10 ⁴). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

本文言語	English
ページ数	1
出版ステータス	Published - 2006 10 19
イベント	55th SPSJ Annual Meeting - Nagoya, Japan 継続期間: 2006 5 24 → 2006 5 26

Conference

Conference	55th SPSJ Annual Meeting
Country	Japan
City	Nagoya
Period	06/5/24 → 06/5/26

ASJC Scopus subject areas

Engineering(all)

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引用スタイル

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title = "Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior",

abstract = "Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.",

keywords = "Cyclic Voltammetry, Electrode-active Material, Galvinoxyl Radical, Radical Polymerization",

author = "Hiroki Ohshiro and Takeo Suga and Hiroyuki Nishide",

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T1 - Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

AU - Ohshiro, Hiroki

AU - Suga, Takeo

AU - Nishide, Hiroyuki

PY - 2006/10/19

Y1 - 2006/10/19

N2 - Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

AB - Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

KW - Cyclic Voltammetry

KW - Electrode-active Material

KW - Galvinoxyl Radical

KW - Radical Polymerization

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