Poly(4-metacryloyl-2,2,6,6-tetramethylpiperidine-1-oxyl) (PTMA) was synthesized as a radical polymer by anionic polymerization. PTMA is rapidly and reversibly oxidized at 0.85 V. The radical formation yield in the sample determined by ESR and SQUID measurements was quantitative. The radical polymer was spin-coated to form a thin film on the ITO substrate. The device with the configuration of Al / PTMA / ITO displayed an ON and OFF state in the conductivity by superimposed voltage. The PTMA devices with different structure (Al / PTMA / Al) and film stack were also discussed.
|ホスト出版物のタイトル||Polymer Preprints, Japan|
|出版ステータス||Published - 2005|
|イベント||54th SPSJ Symposium on Macromolecules - Yamagata|
継続期間: 2005 9月 20 → 2005 9月 22
|Other||54th SPSJ Symposium on Macromolecules|
|Period||05/9/20 → 05/9/22|
ASJC Scopus subject areas