Synthesis of reactive functionalized oligo(p-phenylene sulfide)s

Eishun Tsuchida, Kimihisa Yamamoto, Kenichi Oyaizu, Fumiaki Suzuki, Allan S. Hay, Zhi Yuan Wang

    研究成果: Article

    32 引用 (Scopus)

    抜粋

    Modification of the oligo(phenylene sulfide) chain at the ends with reactive groups such as chloro, bromo, iodo, and carboxyl to enhance its reactivity was performed. α,ω-Dihalooligo(p-phenylene sulfide) was synthesized through the oxidative polymerization of diphenyl disulfide in the presence of bis(4-halophenyl)disulfide. Linear oligo(p-phenylene sulfide) (OPS) terminated by Cl or Br with a high degree of functionality was obtained by a one-pot process. α-Carboxy-OPS was synthesized by the thermolysis of the disulfide bond of the OPS in the presence of an aromatic iodide having a carboxyl group. The carboxy-terminated OPS was used for the synthesis of polyamide-graft-OPS copolymers.

    元の言語English
    ページ(範囲)409-416
    ページ数8
    ジャーナルMacromolecules
    28
    発行部数2
    出版物ステータスPublished - 1995 1 1

      フィンガープリント

    ASJC Scopus subject areas

    • Materials Chemistry

    これを引用

    Tsuchida, E., Yamamoto, K., Oyaizu, K., Suzuki, F., Hay, A. S., & Wang, Z. Y. (1995). Synthesis of reactive functionalized oligo(p-phenylene sulfide)s. Macromolecules, 28(2), 409-416.