SYNTHESIS OF TACTIC POLY(ALKYL METHACRYLATE) HOMO AND COPOLYMERS.

R. D. Allen, Timothy Edward Long, J. E. McGrath

研究成果: Conference contribution

2 被引用数 (Scopus)

抄録

A novel purification route for alkyl methacrylate monomers has been developed. This new route takes advantage of trialkyl aluminums, which react with water and alcohols, to rigorously purify methacrylate monomers. Poly(alkyl methacrylates) can thus be synthesized using a wide variety of available monomers which under conventional purification procedures are not suitable for anionic polymerizations. Homopolymers with controlled molecular weights and fairly narrow molecular weight distributions have been synthesized anionically by taking advantage of the high purity of these polar monomers. Methacrylate-methacrylate block copolymers have also been synthesized with fairly narrow distributions and no detectable homopolymer contamination.

本文言語English
ホスト出版物のタイトルPolymer Science and Technology
編集者Bill M. Culbertson, James E. McGrath
出版社Plenum Press
ページ347-362
ページ数16
31
ISBN(印刷版)0306421097
出版ステータスPublished - 1985 12 1
外部発表はい

ASJC Scopus subject areas

  • Engineering(all)

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