@article{ff094a6a153a459ca446f026e3e0b227,
title = "Synthesis of the C1-C17 Segment of Bafilomycin N",
abstract = "The C1-C17 segment of bafilomycin N has been synthesized. The C1-C11 segment was synthesized by the anti -selective vinylogous Mukaiyama aldol reaction with a chiral vinylketene silyl N, O -acetal and the Horner-Wadsworth-Emmons reaction, whereas C12-C17 was constructed by the syn -selective vinylogous Mukaiyama aldol reaction and the Jung's semipinacol rearrangement. Those segments were connected by the Stille coupling to afford the C1-C17 segment.",
keywords = "Stille coupling, bafilomycin, polypropionate, semipinacol rearrangement, vinylketene silyl N O -acetal, vinylogous Mukaiyama aldol reaction",
author = "Haruka Sato and Seijiro Hosokawa",
note = "Funding Information: We are grateful for the financial support from the Sumitomo Foundation and the Tokyo Biochemical Research Foundation. This work was also supported by Grant-in-Aid for Scientific Research on Innovative Areas {\textquoteleft}Frontier Research on Chemical Communications{\textquoteright} (Grant no. 18H04632).()",
year = "2019",
doi = "10.1055/s-0037-1611727",
language = "English",
volume = "30",
pages = "577--580",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "5",
}