Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites

Masaki Azuma, Yuki Sakai, Takumi Nishikubo, Masaichiro Mizumaki, Tetsu Watanuki, Takashi Mizokawa, Kengo Oka, Hajime Hojo, Makoto Naka

研究成果: Review article査読

7 被引用数 (Scopus)

抄録

Charge distribution changes in Bi- and Pb-3d transition metal perovskite type oxides were examined by comprehensive precise structural analysis, spectroscopy, and theoretical investigations. The change in the depth of the d level of the transition metal caused the intermetallic charge transfer. A temperature-induced charge-transfer transition in chemically modified BiNiO3 results in technologically important negative thermal expansion.

本文言語English
ページ(範囲)1371-1377
ページ数7
ジャーナルDalton Transactions
47
5
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • 無機化学

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