Systematics in the electronic structure of 3d transition-metal compounds

A. E. Bocquet, T. Saitoh, T. Mizokawa, A. Fujimori

研究成果: Article

39 引用 (Scopus)

抄録

We have studied a wide range of 3d transition-metal compounds by a cluster configuration-interaction analysis of the metal 2p core-level photoemission spectra. Deduced values for the charge-transfer energy Δ and the d-d Coulomb repulsion U, defined with respect to the multiplet-averaged energies, show a smooth variation as functions of cation atomic number, ligand and cation valence. Many physical properties, however, show apparently irregular variation, which we attribute to d-d exchange or multiplet effects, which also reflect upon Δeff and Ueff defined with respect to the lowest multiplet energies.

元の言語English
ページ(範囲)11-15
ページ数5
ジャーナルSolid State Communications
83
発行部数1
DOI
出版物ステータスPublished - 1992
外部発表Yes

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Transition metal compounds
metal compounds
Electronic structure
Cations
Positive ions
fine structure
transition metals
electronic structure
Core levels
Photoemission
Charge transfer
cations
Physical properties
Metals
Ligands
configuration interaction
energy
photoelectric emission
physical properties
charge transfer

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

これを引用

Systematics in the electronic structure of 3d transition-metal compounds. / Bocquet, A. E.; Saitoh, T.; Mizokawa, T.; Fujimori, A.

:: Solid State Communications, 巻 83, 番号 1, 1992, p. 11-15.

研究成果: Article

Bocquet, A. E. ; Saitoh, T. ; Mizokawa, T. ; Fujimori, A. / Systematics in the electronic structure of 3d transition-metal compounds. :: Solid State Communications. 1992 ; 巻 83, 番号 1. pp. 11-15.
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