Systematics in the electronic structure of 3d transition-metal compounds

A. E. Bocquet, T. Saitoh, T. Mizokawa, A. Fujimori*

*この研究の対応する著者

研究成果: Article査読

42 被引用数 (Scopus)

抄録

We have studied a wide range of 3d transition-metal compounds by a cluster configuration-interaction analysis of the metal 2p core-level photoemission spectra. Deduced values for the charge-transfer energy Δ and the d-d Coulomb repulsion U, defined with respect to the multiplet-averaged energies, show a smooth variation as functions of cation atomic number, ligand and cation valence. Many physical properties, however, show apparently irregular variation, which we attribute to d-d exchange or multiplet effects, which also reflect upon Δeff and Ueff defined with respect to the lowest multiplet energies.

本文言語English
ページ(範囲)11-15
ページ数5
ジャーナルSolid State Communications
83
1
DOI
出版ステータスPublished - 1992 7月
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 凝縮系物理学
  • 材料化学

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