Temperature dependence of complex permittivity in biodegradable polybutylene succinate

Hiroto Ishikawa, Yoshimichi Ohki

研究成果: Article

15 引用 (Scopus)

抜粋

Polybutylene succinate, a kind of biodegradable polymer, shows thermally stimulated polarization current (TSPC) peaks at around -35 °C and 50 °C. The lower-temperature TSPC peak can be well explained by dipolar polarization. As for the higher-temperature TSPC peak, the permittivity increases more significantly with a decrease in frequency, and the increment in permittivity estimated from the TSPC area agrees with the difference in permittivity at a sufficiently low frequency and at a sufficiently high frequency. It is assumed that a hetero charge layer is formed in front of the two electrodes and that such space charge is responsible for both the higher-temperature TSPC peak and the permittivity increase. The dielectric loss factor also increases with a decrease in frequency, and the increment is in good agreement with the assumption that the dielectric loss is ascribed to conduction loss due to high conductivity at high temperatures. All the results indicate that mobile ions are dominant carrier species in polybutylene succinate.

元の言語English
ページ(範囲)647-651+9
ジャーナルIEEJ Transactions on Fundamentals and Materials
128
発行部数10
DOI
出版物ステータスPublished - 2008 12 1

    フィンガープリント

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

これを引用