The first asymmetric Sonogashira coupling for the enantioselective generation of planar chirality in paracyclophanes

Kazumasa Kanda, Tamami Koike, Kohei Endo, Takanori Shibata

研究成果: Article

32 引用 (Scopus)

抜粋

The double Sonogashira coupling of diiodoparacyclophanes with alkynes proceeded to give planarly chiral dialkynylparacyclophanes; a chiral Pd catalyst, which was prepared in situ from PdCl2(CH 3CN)2 and Taniaphos, realized the first asymmetric Sonogashira coupling with up to ca. 80% ee.

元の言語English
ページ(範囲)1870-1872
ページ数3
ジャーナルChemical Communications
発行部数14
DOI
出版物ステータスPublished - 2009 6 25

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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