The first asymmetric Sonogashira coupling for the enantioselective generation of planar chirality in paracyclophanes

Kazumasa Kanda; Tamami Koike; Kohei Endo; Takanori Shibata

doi:10.1039/b818904h

The first asymmetric Sonogashira coupling for the enantioselective generation of planar chirality in paracyclophanes

Kazumasa Kanda, Tamami Koike, Kohei Endo, Takanori Shibata^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

36 被引用数 (Scopus)

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The double Sonogashira coupling of diiodoparacyclophanes with alkynes proceeded to give planarly chiral dialkynylparacyclophanes; a chiral Pd catalyst, which was prepared in situ from PdCl₂(CH ₃CN)₂ and Taniaphos, realized the first asymmetric Sonogashira coupling with up to ca. 80% ee.

本文言語	English
ページ（範囲）	1870-1872
ページ数	3
ジャーナル	Chemical Communications
号	14
DOI	https://doi.org/10.1039/b818904h
出版ステータス	Published - 2009

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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AU - Shibata, Takanori

PY - 2009

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AB - The double Sonogashira coupling of diiodoparacyclophanes with alkynes proceeded to give planarly chiral dialkynylparacyclophanes; a chiral Pd catalyst, which was prepared in situ from PdCl2(CH 3CN)2 and Taniaphos, realized the first asymmetric Sonogashira coupling with up to ca. 80% ee.

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The first asymmetric Sonogashira coupling for the enantioselective generation of planar chirality in paracyclophanes

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