抄録
The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.
本文言語 | English |
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ページ(範囲) | 5630-5631 |
ページ数 | 2 |
ジャーナル | Journal of the American Chemical Society |
巻 | 125 |
号 | 19 |
DOI | |
出版ステータス | Published - 2003 5月 14 |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)
- 生化学
- コロイド化学および表面化学