The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

Kenichi Oyaizu; Eishun Tsuchida

doi:10.1021/ja021374q

The first oxovanadium ring in [{O=V(salen)}₂(μ-F)][VO(salen)][BF₄] ·(CH₂Cl₂)_x crystals

Kenichi Oyaizu, Eishun Tsuchida

先進理工学部

研究成果: Article › 査読

17 被引用数 (Scopus)

抄録

The crystal structure of [{OV^V(salen)}₂(μ-F)][V^IVO(salen)][BF₄]·(CH₂Cl₂)_x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH₂Cl₂ molecules.

本文言語	English
ページ（範囲）	5630-5631
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	125
号	19
DOI	https://doi.org/10.1021/ja021374q
出版ステータス	Published - 2003 5 14

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

文献へのアクセス

10.1021/ja021374q

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引用スタイル

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