The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

Kenichi Oyaizu, Eishun Tsuchida

研究成果: Article査読

17 被引用数 (Scopus)

抄録

The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

本文言語English
ページ(範囲)5630-5631
ページ数2
ジャーナルJournal of the American Chemical Society
125
19
DOI
出版ステータスPublished - 2003 5 14

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

フィンガープリント 「The first oxovanadium ring in [{O=V(salen)}<sub>2</sub>(μ-F)][VO(salen)][BF<sub>4</sub>] ·(CH<sub>2</sub>Cl<sub>2</sub>)<sub>x</sub> crystals」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル