The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

Kenichi Oyaizu; Eishun Tsuchida

doi:10.1021/ja021374q

The first oxovanadium ring in [{O=V(salen)}₂(μ-F)][VO(salen)][BF₄] ·(CH₂Cl₂)_x crystals

Kenichi Oyaizu, Eishun Tsuchida^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

17 被引用数 (Scopus)

抄録

The crystal structure of [{OV^V(salen)}₂(μ-F)][V^IVO(salen)][BF₄]·(CH₂Cl₂)_x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH₂Cl₂ molecules.

本文言語	English
ページ（範囲）	5630-5631
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	125
号	19
DOI	https://doi.org/10.1021/ja021374q
出版ステータス	Published - 2003 5 14

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

文献へのアクセス

10.1021/ja021374q

他のファイルとリンク

フィンガープリント

「The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{7bb441a8b31d4c9f8d816fab223feae8,

title = "The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals",

abstract = "The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 {\AA} that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.",

author = "Kenichi Oyaizu and Eishun Tsuchida",

year = "2003",

month = may,

day = "14",

doi = "10.1021/ja021374q",

language = "English",

volume = "125",

pages = "5630--5631",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

AU - Oyaizu, Kenichi

AU - Tsuchida, Eishun

PY - 2003/5/14

Y1 - 2003/5/14

N2 - The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

AB - The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

UR - http://www.scopus.com/inward/record.url?scp=0038634977&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038634977&partnerID=8YFLogxK

U2 - 10.1021/ja021374q

DO - 10.1021/ja021374q

M3 - Article

C2 - 12733891

AN - SCOPUS:0038634977

VL - 125

SP - 5630

EP - 5631

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 19

ER -