@article{da3ae4daf6c54298b4ee969c53a569d4,
title = "The first total synthesis and structural determination of actinopyrone A",
abstract = "Actinopyrone A (1) has been synthesized by using our developed remote stereoinduction, Kocienski olefination, Horner-Wadsworth-Emmons olefination, and reductive de-conjugation of the vinylpyrone. A concise method of O-methylation to obtain the γ-pyrone has also been established.",
keywords = "4-Pyrone, Actinopyrone A, Reductive de-conjugation, Remote stereoinduction, Structural determination, Total synthesis",
author = "Seijiro Hosokawa and Kazuya Yokota and Keisuke Imamura and Yasuaki Suzuki and Masataka Kawarasaki and Kuniaki Tatsuta",
note = "Funding Information: Special thanks to Drs. T. Adachi, A. Kawashima, and Y. Terui in Taisho Pharmaceutical Co. Ltd. to give us an authentic sample of actinopyrone A ( 1 ) and useful information including spectral data and properties. K.I. thanks JSPS Research Fellowships for Young Scientists. The authors are also grateful for financial support to 21COE {\textquoteleft}Center for Practical Nano-Chemistry{\textquoteright}, Consolidated Research Institute for Advanced Science and Medical Care, and Grant-in-Aid for Scientific Research (A), Scientific Research (C), and Scientific Research on Priority Areas 16073220 from The Ministry of Education, Culture, Sports, Science and Technology (MEXT).",
year = "2006",
month = jul,
day = "24",
doi = "10.1016/j.tetlet.2006.05.028",
language = "English",
volume = "47",
pages = "5415--5418",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "30",
}