The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution

Koji Ishihara, Thomas Wilson Swaddle

研究成果: Article

12 引用 (Scopus)

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The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.

元の言語English
ページ(範囲)2168-2170
ページ数3
ジャーナルCanadian Journal of Chemistry
64
発行部数11
DOI
出版物ステータスPublished - 1986 1 1

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ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

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