The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution

Koji Ishihara; Thomas Wilson Swaddle

doi:10.1139/v86-356

The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution

Koji Ishihara, Thomas Wilson Swaddle

研究成果: Article › 査読

12 被引用数 (Scopus)

抄録

The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O₄ at 63.4°C is +19 cm³ mol^-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.

本文言語	English
ページ（範囲）	2168-2170
ページ数	3
ジャーナル	Canadian Journal of Chemistry
巻	64
号	11
DOI	https://doi.org/10.1139/v86-356
出版ステータス	Published - 1986
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)
有機化学

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abstract = "The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.",

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N2 - The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.

AB - The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.

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The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution

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