The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution

Koji Ishihara; Thomas Wilson Swaddle

doi:10.1139/v86-356

The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution

Koji Ishihara, Thomas Wilson Swaddle

研究成果: Article

12 引用（Scopus）

抜粋

The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O₄ at 63.4°C is +19 cm³ mol^-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.

元の言語	English
ページ（範囲）	2168-2170
ページ数	3
ジャーナル	Canadian Journal of Chemistry
巻	64
発行部数	11
DOI	https://doi.org/10.1139/v86-356
出版物ステータス	Published - 1986 1 1
外部発表	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Organic Chemistry

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10.1139/v86-356

フィンガープリント The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

これを引用

Ishihara, K., & Swaddle, T. W. (1986). The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution. Canadian Journal of Chemistry, 64(11), 2168-2170. https://doi.org/10.1139/v86-356

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