The single crystal metal-non-aqueous solvent interface. Underpotential deposition of Cd on Ag (111) in propylene carbonate

Xing Xue-Kun*, P. Abel, R. McIntyre, Daniel Alberto Scherson

*この研究の対応する著者

研究成果: Article査読

15 被引用数 (Scopus)

抄録

The underpotential deposition of cadmium on Ag (111) in propylene carbonate using either lithium perchlorate or tetra-n-butylammonium perchlorate as supporting electrolytes has been found to yield sharp and well defined voltammetric peaks. The results obtained in aqueous LiClO4 and tetraethylammonium perchlorate solutions for the same UPD-host metal system were, however, found to be different from those in propylene carbonate, particularly in the case of LiClO4 for which the voltammetry was characterized by broad and ill-defined features. This novel solvent-induced effect has been attributed to differences in the extent of specific adsorption of the perchlorate anion in water and PC and/or to solvent-metal substrate interactions.

本文言語English
ページ(範囲)261-271
ページ数11
ジャーナルJournal of Electroanalytical Chemistry
216
1-2
DOI
出版ステータスPublished - 1987 9 1
外部発表はい

ASJC Scopus subject areas

  • 分析化学
  • 化学工学(全般)
  • 電気化学

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