The synthesis of meso conjugated heterocycle porphyrins and their self-assembly via hydrogen bonds

Satoshi Arai, Daisuke Niwa, Shinji Takeoka, Hiroyuki Nishide

研究成果: Paper査読

抄録

We have synthesized the uracil units conjugated to a porphyrin, of which atropisomerization was regulated by steric replusion between methyl substituents at the pyrrole ß-position. The αα isomer formed a dimmer structure with two melamine derivatives as complementary units via hydrogen bonds. The NMR experiment indicated that the stable dimmer structure formed in toluene diluted solution and the αβ isomer formed an array structure in high concentration. The different structure was discussed from the view of the dioxygen binding property.

本文言語English
ページ数1
出版ステータスPublished - 2006 10 19
イベント55th SPSJ Annual Meeting - Nagoya, Japan
継続期間: 2006 5 242006 5 26

Conference

Conference55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period06/5/2406/5/26

ASJC Scopus subject areas

  • Engineering(all)

フィンガープリント 「The synthesis of meso conjugated heterocycle porphyrins and their self-assembly via hydrogen bonds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル