Thermodynamic relations in correlated systems

Shinji Watanabe, Masatoshi Imada

研究成果: Article

11 引用 (Scopus)

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Several useful thermodynamic relations are derived for metal-insulator transitions, as generalizations of the Clausius-Clapeyron and Eherenfest theorems. These relations hold in any spatial dimensions and at any temperatures. First, they relate several thermodynamic quantities to the slope of the metal-insulator phase boundary drawn in the plane of the chemical potential and the Coulomb interaction in the phase diagram of the Hubbard model. The relations impose constraints on the critical properties of the Mott transition. These thermodynamic relations are indeed confirmed to be satisfied in the cases of the one- and two-dimensional Hubbard models. One of these relations yields that at the continuous Mott transition with a diverging charge compressibility, the doublon susceptibility also diverges. The constraints on the shapes of the phase boundary containing a first-order metal-insulator transition at finite temperatures are clarified based on the thermodynamic relations. For example, the first-order phase boundary is parallel to the temperature axis asymptotically in the zero temperature limit. The applicability of the thermodynamic relations are not restricted only to the metal-insulator transition of the Hubbard model, but also hold in correlated systems with any types of phases in general. We demonstrate such examples in an extended Hubbard model with intersite Coulomb repulsion containing the charge order phase.

元の言語English
ページ(範囲)3341-3350
ページ数10
ジャーナルjournal of the physical society of japan
73
発行部数12
DOI
出版物ステータスPublished - 2004 12 1
外部発表Yes

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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