Total syntheses of (-)-scabronines G and A, and (-)-episcabronine A

Yu Kobayakawa; Masahisa Nakada

doi:10.1002/anie.201303224

Total syntheses of (-)-scabronines G and A, and (-)-episcabronine A

Yu Kobayakawa, Masahisa Nakada^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

26 被引用数 (Scopus)

抄録

Making scab(ronine)s: The total synthesis of (-)-scabronine G features a highly stereoselective oxidative dearomatization/intramolecular inverse-electron-demand Diels-Alder reaction cascade, and the first total synthesis of (-)-scabronine A comprises a highly stereoselective oxa-Michael/protonation/acetalization cascade. The first total synthesis of (-)-episcabronine A includes another highly stereoselective cascade.

本文言語	English
ページ（範囲）	7569-7573
ページ数	5
ジャーナル	Angewandte Chemie - International Edition
巻	52
号	29
DOI	https://doi.org/10.1002/anie.201303224
出版ステータス	Published - 2013 7 15

ASJC Scopus subject areas

触媒
化学 (全般)

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10.1002/anie.201303224

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author = "Yu Kobayakawa and Masahisa Nakada",

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AB - Making scab(ronine)s: The total synthesis of (-)-scabronine G features a highly stereoselective oxidative dearomatization/intramolecular inverse-electron-demand Diels-Alder reaction cascade, and the first total synthesis of (-)-scabronine A comprises a highly stereoselective oxa-Michael/protonation/acetalization cascade. The first total synthesis of (-)-episcabronine A includes another highly stereoselective cascade.

KW - cycloaddition

KW - enantioselectivity

KW - medium-ring compounds

KW - natural products

KW - total synthesis

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Total syntheses of (-)-scabronines G and A, and (-)-episcabronine A

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