Total synthesis of (+)-epoxyquinols A and B

Mitsuru Shoji, Junichiro Yamaguchi, Hideaki Kakeya, Hiroyuki Osada, Yujiro Hayashi

研究成果: Article

88 引用 (Scopus)

抜粋

A highly stereoselective HfCl4-mediated Diels-Alder reaction of furan and the chiral acrylate ester of Corey's auxiliary to subsequently give 1, and the realization of the postulated biosynthetic pathway for the construction of epoxyquinols A and B, namely, oxidative 6π electrocyclization, followed by Diels-Alder reaction of the unprotected monomer are the key steps in the asymmetric total synthesis of (+)-epoxyquinols A and B.

元の言語English
ページ(範囲)3192-3194
ページ数3
ジャーナルAngewandte Chemie - International Edition
41
発行部数17
DOI
出版物ステータスPublished - 2002 9 2

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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