Total synthesis of (+)-epoxyquinols A and B

Mitsuru Shoji, Junichiro Yamaguchi, Hideaki Kakeya, Hiroyuki Osada, Yujiro Hayashi

研究成果: Article

86 引用 (Scopus)

抄録

A highly stereoselective HfCl4-mediated Diels-Alder reaction of furan and the chiral acrylate ester of Corey's auxiliary to subsequently give 1, and the realization of the postulated biosynthetic pathway for the construction of epoxyquinols A and B, namely, oxidative 6π electrocyclization, followed by Diels-Alder reaction of the unprotected monomer are the key steps in the asymmetric total synthesis of (+)-epoxyquinols A and B.

元の言語English
ページ(範囲)3192-3194
ページ数3
ジャーナルAngewandte Chemie - International Edition
41
発行部数17
DOI
出版物ステータスPublished - 2002 9 2
外部発表Yes

Fingerprint

Esters
Monomers
Biosynthetic Pathways
epoxyquinol A
epoxyquinol B
furan
acrylic acid

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Total synthesis of (+)-epoxyquinols A and B. / Shoji, Mitsuru; Yamaguchi, Junichiro; Kakeya, Hideaki; Osada, Hiroyuki; Hayashi, Yujiro.

:: Angewandte Chemie - International Edition, 巻 41, 番号 17, 02.09.2002, p. 3192-3194.

研究成果: Article

Shoji, Mitsuru ; Yamaguchi, Junichiro ; Kakeya, Hideaki ; Osada, Hiroyuki ; Hayashi, Yujiro. / Total synthesis of (+)-epoxyquinols A and B. :: Angewandte Chemie - International Edition. 2002 ; 巻 41, 番号 17. pp. 3192-3194.
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