Transformation of layered docosyltrimethyl- and docosyltriethylammonium silicates derived from kanemite into precursors for ordered mesoporous silicas

Tatsuo Kimura, Daigo Itoh, Tetsuro Shigeno, Kazuyuki Kuroda

研究成果: Article

21 引用 (Scopus)

抜粋

The transformation of layered silicate-surfactant materials derived from a layered polysilicate kanemite into precursors for ordered mesoporous silicas was investigated. When kanemite was allowed to react with docosyltrimethylammonium (C22TMA) and docosyltriethylammonium (C22TEA) surfactants, layered C22-TMA- and C22TEA-silicate materials were formed. The 29Si MAS NMR spectra of the layered intermediates clearly indicated that fragmented silicate sheets were present in the silicate-surfactant materials. These layered materials can be transformed by acid treatment into mesostructured precursors with three-dimensional (3-d) silicate networks that afford uniform mesopores after the removal of the surfactants. Ordered mesoporous silica with a 2-d hexagonal structure (FSM-16) can be obtained by using C22TEA with a larger headgroup. The results here successfully support the proposed formation mechanism of FSM-16, which consists of assembling of fragmented layered silicate sheets with surfactants and the subsequent structural transformation to the 2-d hexagonal mesophase.

元の言語English
ページ(範囲)9574-9577
ページ数4
ジャーナルLangmuir
18
発行部数24
DOI
出版物ステータスPublished - 2002 11 26

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

フィンガープリント Transformation of layered docosyltrimethyl- and docosyltriethylammonium silicates derived from kanemite into precursors for ordered mesoporous silicas' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用