TY - JOUR
T1 - Treatment of LCO fractions on zeolite beta
AU - Matsukata, M.
AU - Sharma, P.
AU - Iguchi, Y.
AU - Sekine, Y.
AU - Kikuchi, E.
PY - 2003/9/1
Y1 - 2003/9/1
N2 - Beta zeolite catalysts with different crystal sizes and similar acid strengths were synthesized in a "Steam-Assisted conversion (SAC)" technique. Pt loaded H-beta with an optimized crystal size of 600 nm showed high activity for hydrotreatment of tetralin by producing alkylbenzenes through area and low coke deposition. Isomerization reaction, which was expected to occur on the zeolite surface, was reduced considerably since tetralin interacted with strong Brönsted acid sites as soon as it penetrated the pore of the zeolite and underwent cracking to form linear hydrocarbons, C6 and C7 aromatics products. The method of supporting platinum on the zeolite had a significant effect on the activity of catalyst. For loading platinum of beta zeolite, ion exchange was a suitable method as it helped in well dispersion of platinum on the zeolite surface and inside the micropore.
AB - Beta zeolite catalysts with different crystal sizes and similar acid strengths were synthesized in a "Steam-Assisted conversion (SAC)" technique. Pt loaded H-beta with an optimized crystal size of 600 nm showed high activity for hydrotreatment of tetralin by producing alkylbenzenes through area and low coke deposition. Isomerization reaction, which was expected to occur on the zeolite surface, was reduced considerably since tetralin interacted with strong Brönsted acid sites as soon as it penetrated the pore of the zeolite and underwent cracking to form linear hydrocarbons, C6 and C7 aromatics products. The method of supporting platinum on the zeolite had a significant effect on the activity of catalyst. For loading platinum of beta zeolite, ion exchange was a suitable method as it helped in well dispersion of platinum on the zeolite surface and inside the micropore.
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M3 - Conference article
AN - SCOPUS:1042266802
VL - 48
SP - 172
EP - 173
JO - American Chemical Society, Division of Petroleum Chemistry, Preprints
JF - American Chemical Society, Division of Petroleum Chemistry, Preprints
SN - 0569-3799
IS - 3
T2 - American Chemical Society, Division of Petroleum Chemistry, Preprints
Y2 - 7 September 2003 through 11 September 2003
ER -