Trimethylphosphine-Promoted Alcoholysis of α,β-Unsaturated Imides and α,β-Unsaturated Esters

Haruka Sato, Seijiro Hosokawa

    研究成果: Article

    抄録

    α,β-Unsaturated imides and α,β-unsaturated esters were found to undergo alcoholysis in the presence of trimethylphosphine. The reaction is initiated by nucleophilic addition of trimethylphosphine to the double bond of the α,β-unsaturated carbonyl compound. Saturated imides also undergo the alcoholysis in the presence of the corresponding α,β-unsaturated imide.

    元の言語English
    ページ(範囲)1343-1349
    ページ数7
    ジャーナルSynthesis (Germany)
    50
    発行部数6
    DOI
    出版物ステータスPublished - 2018 3 15

    Fingerprint

    Imides
    Carbonyl compounds
    Esters

    ASJC Scopus subject areas

    • Catalysis
    • Organic Chemistry

    これを引用

    @article{c15bbbc3bcac4fa98b4abb8088415aa9,
    title = "Trimethylphosphine-Promoted Alcoholysis of α,β-Unsaturated Imides and α,β-Unsaturated Esters",
    abstract = "α,β-Unsaturated imides and α,β-unsaturated esters were found to undergo alcoholysis in the presence of trimethylphosphine. The reaction is initiated by nucleophilic addition of trimethylphosphine to the double bond of the α,β-unsaturated carbonyl compound. Saturated imides also undergo the alcoholysis in the presence of the corresponding α,β-unsaturated imide.",
    keywords = "alcoholysis, conjugate addition, transesterification, trimethylphosphine, unsaturated esters, unsaturated imides",
    author = "Haruka Sato and Seijiro Hosokawa",
    year = "2018",
    month = "3",
    day = "15",
    doi = "10.1055/s-0036-1589162",
    language = "English",
    volume = "50",
    pages = "1343--1349",
    journal = "Synthesis (Germany)",
    issn = "0039-7881",
    publisher = "Georg Thieme Verlag",
    number = "6",

    }

    TY - JOUR

    T1 - Trimethylphosphine-Promoted Alcoholysis of α,β-Unsaturated Imides and α,β-Unsaturated Esters

    AU - Sato, Haruka

    AU - Hosokawa, Seijiro

    PY - 2018/3/15

    Y1 - 2018/3/15

    N2 - α,β-Unsaturated imides and α,β-unsaturated esters were found to undergo alcoholysis in the presence of trimethylphosphine. The reaction is initiated by nucleophilic addition of trimethylphosphine to the double bond of the α,β-unsaturated carbonyl compound. Saturated imides also undergo the alcoholysis in the presence of the corresponding α,β-unsaturated imide.

    AB - α,β-Unsaturated imides and α,β-unsaturated esters were found to undergo alcoholysis in the presence of trimethylphosphine. The reaction is initiated by nucleophilic addition of trimethylphosphine to the double bond of the α,β-unsaturated carbonyl compound. Saturated imides also undergo the alcoholysis in the presence of the corresponding α,β-unsaturated imide.

    KW - alcoholysis

    KW - conjugate addition

    KW - transesterification

    KW - trimethylphosphine

    KW - unsaturated esters

    KW - unsaturated imides

    UR - http://www.scopus.com/inward/record.url?scp=85040776816&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=85040776816&partnerID=8YFLogxK

    U2 - 10.1055/s-0036-1589162

    DO - 10.1055/s-0036-1589162

    M3 - Article

    VL - 50

    SP - 1343

    EP - 1349

    JO - Synthesis (Germany)

    JF - Synthesis (Germany)

    SN - 0039-7881

    IS - 6

    ER -