Tuning the morphology of electroactive polythiophene nano-structures

Bartlomiej Kolodziejczyk, Orawan Winther-Jensen, Robert Kerr, Paul Firbas, Bjorn Winther Jensen

研究成果: Article

3 引用 (Scopus)

抄録

The self-assembly of thiophene monomers and the subsequent oxidative polymerization of them has been studied using the vapour phase polymerization (VPP) platform. A variety of nano-structures were obtained by varying the polymerization conditions with regard to temperature, time, addition of a secondary oxidant and crystal formation in the oxidant layer. The electrochemical and physical characterizations of these nano-structured polythiophene materials were performed using cyclic voltammetry, electron microscopy, UV-vis spectroscopy, conductivity, contact angle and BET surface area measurements. The presence of nano-structures indeed enhances the redox capacity and increases the active surface area compared to the analogue film without nanostructures. The hydrophobicity of the polymeric film is also tuneable from different nano-structures forming on top of the film.

元の言語English
ページ(範囲)60-66
ページ数7
ジャーナルReactive and Functional Polymers
86
DOI
出版物ステータスPublished - 2015
外部発表Yes

Fingerprint

polymerization
Polymerization
Tuning
Oxidants
oxidant
Polymers
surface area
Thiophenes
Nanostructures
hydrophobicity
Thiophene
Motion Pictures
Hydrophobicity
Ultraviolet spectroscopy
electron microscopy
Hydrophobic and Hydrophilic Interactions
Polymer films
Self assembly
Electron microscopy
Cyclic voltammetry

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics
  • Chemistry(all)
  • Chemical Engineering(all)
  • Environmental Chemistry
  • Biochemistry

これを引用

Kolodziejczyk, B., Winther-Jensen, O., Kerr, R., Firbas, P., & Winther Jensen, B. (2015). Tuning the morphology of electroactive polythiophene nano-structures. Reactive and Functional Polymers, 86, 60-66. https://doi.org/10.1016/j.reactfunctpolym.2014.11.010

Tuning the morphology of electroactive polythiophene nano-structures. / Kolodziejczyk, Bartlomiej; Winther-Jensen, Orawan; Kerr, Robert; Firbas, Paul; Winther Jensen, Bjorn.

:: Reactive and Functional Polymers, 巻 86, 2015, p. 60-66.

研究成果: Article

Kolodziejczyk, B, Winther-Jensen, O, Kerr, R, Firbas, P & Winther Jensen, B 2015, 'Tuning the morphology of electroactive polythiophene nano-structures', Reactive and Functional Polymers, 巻. 86, pp. 60-66. https://doi.org/10.1016/j.reactfunctpolym.2014.11.010
Kolodziejczyk, Bartlomiej ; Winther-Jensen, Orawan ; Kerr, Robert ; Firbas, Paul ; Winther Jensen, Bjorn. / Tuning the morphology of electroactive polythiophene nano-structures. :: Reactive and Functional Polymers. 2015 ; 巻 86. pp. 60-66.
@article{bcaa5accef4248ac9a20598d30762f84,
title = "Tuning the morphology of electroactive polythiophene nano-structures",
abstract = "The self-assembly of thiophene monomers and the subsequent oxidative polymerization of them has been studied using the vapour phase polymerization (VPP) platform. A variety of nano-structures were obtained by varying the polymerization conditions with regard to temperature, time, addition of a secondary oxidant and crystal formation in the oxidant layer. The electrochemical and physical characterizations of these nano-structured polythiophene materials were performed using cyclic voltammetry, electron microscopy, UV-vis spectroscopy, conductivity, contact angle and BET surface area measurements. The presence of nano-structures indeed enhances the redox capacity and increases the active surface area compared to the analogue film without nanostructures. The hydrophobicity of the polymeric film is also tuneable from different nano-structures forming on top of the film.",
keywords = "Conducting polymers, Nano-structured materials, Nano-structures, Polythiophene, Vapor phase polymerization",
author = "Bartlomiej Kolodziejczyk and Orawan Winther-Jensen and Robert Kerr and Paul Firbas and {Winther Jensen}, Bjorn",
year = "2015",
doi = "10.1016/j.reactfunctpolym.2014.11.010",
language = "English",
volume = "86",
pages = "60--66",
journal = "Reactive and Functional Polymers",
issn = "1381-5148",
publisher = "Elsevier",

}

TY - JOUR

T1 - Tuning the morphology of electroactive polythiophene nano-structures

AU - Kolodziejczyk, Bartlomiej

AU - Winther-Jensen, Orawan

AU - Kerr, Robert

AU - Firbas, Paul

AU - Winther Jensen, Bjorn

PY - 2015

Y1 - 2015

N2 - The self-assembly of thiophene monomers and the subsequent oxidative polymerization of them has been studied using the vapour phase polymerization (VPP) platform. A variety of nano-structures were obtained by varying the polymerization conditions with regard to temperature, time, addition of a secondary oxidant and crystal formation in the oxidant layer. The electrochemical and physical characterizations of these nano-structured polythiophene materials were performed using cyclic voltammetry, electron microscopy, UV-vis spectroscopy, conductivity, contact angle and BET surface area measurements. The presence of nano-structures indeed enhances the redox capacity and increases the active surface area compared to the analogue film without nanostructures. The hydrophobicity of the polymeric film is also tuneable from different nano-structures forming on top of the film.

AB - The self-assembly of thiophene monomers and the subsequent oxidative polymerization of them has been studied using the vapour phase polymerization (VPP) platform. A variety of nano-structures were obtained by varying the polymerization conditions with regard to temperature, time, addition of a secondary oxidant and crystal formation in the oxidant layer. The electrochemical and physical characterizations of these nano-structured polythiophene materials were performed using cyclic voltammetry, electron microscopy, UV-vis spectroscopy, conductivity, contact angle and BET surface area measurements. The presence of nano-structures indeed enhances the redox capacity and increases the active surface area compared to the analogue film without nanostructures. The hydrophobicity of the polymeric film is also tuneable from different nano-structures forming on top of the film.

KW - Conducting polymers

KW - Nano-structured materials

KW - Nano-structures

KW - Polythiophene

KW - Vapor phase polymerization

UR - http://www.scopus.com/inward/record.url?scp=84916608397&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84916608397&partnerID=8YFLogxK

U2 - 10.1016/j.reactfunctpolym.2014.11.010

DO - 10.1016/j.reactfunctpolym.2014.11.010

M3 - Article

AN - SCOPUS:84916608397

VL - 86

SP - 60

EP - 66

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

SN - 1381-5148

ER -