Two-step synthesis of a red-emissive warped nanographene derivative: Via a ten-fold C-H borylation

Kenta Kato, Hsing An Lin, Motonobu Kuwayama, Mai Nagase, Yasutomo Segawa*, Lawrence T. Scott, Kenichiro Itami

*この研究の対応する著者

研究成果: Article査読

12 被引用数 (Scopus)

抄録

The regioselective ten-fold borylation of warped nanographene (WNG: C80H30) was achieved by modifying the reaction conditions of a previously reported Ir-catalyzed C-H borylation, affording decaborylated WNG in high yield (75%) from pristine WNG. The solid-state structure of decaborylated WNG was confirmed by X-ray crystallography. Corresponding decaarylated WNGs containing electron-withdrawing and -donating groups were synthesized from decaborylated WNG using Suzuki-Miyaura cross-coupling reactions to afford the red-emissive warped nanographene derivative.

本文言語English
ページ(範囲)9038-9041
ページ数4
ジャーナルChemical Science
10
39
DOI
出版ステータスPublished - 2019
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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