Ultrahigh vacuum/transfer system for electrochemical studies

Kuilong Wang*, Steve Eppell, Gary S. Chottiner, Daniel Alberto Scherson

*この研究の対応する著者

研究成果: Article査読

12 被引用数 (Scopus)

抄録

An ultrahigh vacuum/transfer system has been designed and constructed to investigate the electrochemical properties of surfaces prepared and characterized in ultrahigh vacuum (UHV). One of the unique features of this system is a self-contained electrochemical cell with a built-in dynamic hydrogen reference electrode which can be charged and tested in situ. The capabilities of the apparatus were demonstrated by examining the cyclic voltammetry of c(4×2)CO/Ni(111) surfaces (formed in UHV) in 0.1 M KOH electrolytes. The first linear scan in the positive direction revealed characteristic features associated with the quantitative electrooxidation of the adsorbed CO not observed in specimens exposed to an oxygen containing atmosphere.

本文言語English
ページ(範囲)1066-1070
ページ数5
ジャーナルReview of Scientific Instruments
64
4
DOI
出版ステータスPublished - 1993 12 1
外部発表はい

ASJC Scopus subject areas

  • 器械工学
  • 物理学および天文学(その他)

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