抄録
An ultrahigh vacuum/transfer system has been designed and constructed to investigate the electrochemical properties of surfaces prepared and characterized in ultrahigh vacuum (UHV). One of the unique features of this system is a self-contained electrochemical cell with a built-in dynamic hydrogen reference electrode which can be charged and tested in situ. The capabilities of the apparatus were demonstrated by examining the cyclic voltammetry of c(4×2)CO/Ni(111) surfaces (formed in UHV) in 0.1 M KOH electrolytes. The first linear scan in the positive direction revealed characteristic features associated with the quantitative electrooxidation of the adsorbed CO not observed in specimens exposed to an oxygen containing atmosphere.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 1066-1070 |
| ページ数 | 5 |
| ジャーナル | Review of Scientific Instruments |
| 巻 | 64 |
| 発行部数 | 4 |
| DOI | |
| 出版物ステータス | Published - 1993 12 1 |
| 外部発表 | Yes |
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ASJC Scopus subject areas
- Instrumentation
- Physics and Astronomy (miscellaneous)
これを引用
Ultrahigh vacuum/transfer system for electrochemical studies. / Wang, Kuilong; Eppell, Steve; Chottiner, Gary S.; Scherson, Daniel Alberto.
：: Review of Scientific Instruments, 巻 64, 番号 4, 01.12.1993, p. 1066-1070.研究成果: Article
}
TY - JOUR
T1 - Ultrahigh vacuum/transfer system for electrochemical studies
AU - Wang, Kuilong
AU - Eppell, Steve
AU - Chottiner, Gary S.
AU - Scherson, Daniel Alberto
PY - 1993/12/1
Y1 - 1993/12/1
N2 - An ultrahigh vacuum/transfer system has been designed and constructed to investigate the electrochemical properties of surfaces prepared and characterized in ultrahigh vacuum (UHV). One of the unique features of this system is a self-contained electrochemical cell with a built-in dynamic hydrogen reference electrode which can be charged and tested in situ. The capabilities of the apparatus were demonstrated by examining the cyclic voltammetry of c(4×2)CO/Ni(111) surfaces (formed in UHV) in 0.1 M KOH electrolytes. The first linear scan in the positive direction revealed characteristic features associated with the quantitative electrooxidation of the adsorbed CO not observed in specimens exposed to an oxygen containing atmosphere.
AB - An ultrahigh vacuum/transfer system has been designed and constructed to investigate the electrochemical properties of surfaces prepared and characterized in ultrahigh vacuum (UHV). One of the unique features of this system is a self-contained electrochemical cell with a built-in dynamic hydrogen reference electrode which can be charged and tested in situ. The capabilities of the apparatus were demonstrated by examining the cyclic voltammetry of c(4×2)CO/Ni(111) surfaces (formed in UHV) in 0.1 M KOH electrolytes. The first linear scan in the positive direction revealed characteristic features associated with the quantitative electrooxidation of the adsorbed CO not observed in specimens exposed to an oxygen containing atmosphere.
UR - http://www.scopus.com/inward/record.url?scp=36449001818&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=36449001818&partnerID=8YFLogxK
U2 - 10.1063/1.1144179
DO - 10.1063/1.1144179
M3 - Article
AN - SCOPUS:36449001818
VL - 64
SP - 1066
EP - 1070
JO - Review of Scientific Instruments
JF - Review of Scientific Instruments
SN - 0034-6748
IS - 4
ER -