Unidirectional orientation of methylene blue intercalated in K4Nb6O17 single crystal

Ryozo Kaito, Kazuyuki Kuroda, Makoto Ogawa*

*この研究の対応する著者

研究成果: Article査読

31 被引用数 (Scopus)

抄録

Intercalation of methylene blue into K4Nb6O17 single crystals was investigated for the construction of hybrid materials with three-dimensional anisotropy. By the reaction of K4Nb6O17 with a methylene blue aqueous solution in the presence of propylamine, methylene blue/K4Nb6O17 intercalation compounds were obtained. The basal spacing increased to 3.0 nm, and the macroscopic thickness of the crystal also increased. The regularity in the ac plane did not change by the reaction as evidenced by the in-plane X-ray diffraction measurements. Polarized absorption spectra showed a dichroism showing that the methylene blue/K4Nb6O17 intercalation compounds possess three-dimensionally confined nanostructures.

本文言語English
ページ(範囲)4043-4047
ページ数5
ジャーナルJournal of Physical Chemistry B
107
17
DOI
出版ステータスPublished - 2003 5 1
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 表面、皮膜および薄膜
  • 材料化学

フィンガープリント

「Unidirectional orientation of methylene blue intercalated in K<sub>4</sub>Nb<sub>6</sub>O<sub>17</sub> single crystal」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル