抄録
The chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon-carbon bond cleavage was presented. It was shown that i-Pr2Zn do not add to the aldehyde moiety but to the 2-position of the bipyridine to afford possessing a quaternary carbon atom in a yield of 69%. It was found that the i-Pr2Zn does not add to the aldehyde but to the 2-position of the bipyridine ring by destroying the aromaticity of the pyridine ring.
本文言語 | English |
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ページ(範囲) | 217-218 |
ページ数 | 2 |
ジャーナル | Journal of the Chemical Society. Perkin Transactions 1 |
号 | 3 |
DOI | |
出版ステータス | Published - 2001 2月 7 |
外部発表 | はい |
ASJC Scopus subject areas
- 化学 (全般)