Vapour-phase polymerization of pyrrole and 3,4-ethylenedioxythiophene using iron(III) 2,4,6-trimethylbenzenesulfonate

Priya Subramanian, Noel Clark, Bjorn Winther Jensen, Douglas MacFarlane, Leone Spiccia*

*この研究の対応する著者

研究成果: Article査読

31 被引用数 (Scopus)

抄録

A new iron(iii) 2,4,6-trimethylbenzenesulfonate (MSA) with composition [Fe(OH2)5(MSA)3] has been prepared from the reaction of Fe(OH)3xH2O and three molar equivalents of 2,4,6-trimethylbenzenesulfonic acid and used as oxidant in the preparation of highly conducting polypyrrole (PPy) and poly(3,4-ethylenedioxythiophene) (PEDOT) films for the first time. PPy and PEDOT films grown on non-conducting overhead transparency (polyethylene terephthalate films) using a vapour phase polymerization technique exhibited very high conductivities; 200 20 S cm -1 for PPy and 1000 80 S cm-1 for PEDOT.

本文言語English
ページ(範囲)133-139
ページ数7
ジャーナルAustralian Journal of Chemistry
62
2
DOI
出版ステータスPublished - 2009
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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