Which is reactive in alkaline solution, boronate ion or boronic acid? Kinetic evidence for reactive trigonal boronic acid in an alkaline solution

Satoshi Iwatsuki, Shihoko Nakajima, Masahiko Inamo, Hideo D. Takagi, Koji Ishihara

研究成果: Article

46 引用 (Scopus)

抜粋

That boronic acid is a reactive species toward a diol moiety even in an alkaline solution and that the boronate ion is not very reactive were demonstrated by the estimated upper limit of the rate constants for the reactions of some boronic acids with 2,2′-biphenol and 2,3-dihydroxynaphthalene in a neutral-alkaline solution, which will correct a common misunderstanding in boron chemistry and would renew the idea of effective boronic acid sensor design for carbohydrates.

元の言語English
ページ(範囲)354-356
ページ数3
ジャーナルInorganic Chemistry
46
発行部数2
DOI
出版物ステータスPublished - 2007 1 22

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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